The etching technology currently used in the solar industry is mostly based on wet chemical processing. Plasmaenhanced dry chemical etching at atmospheric pressure is an alternative to the existing technology, especially when combined with similar process technologies, for example plasma-enhanced deposition techniques at atmospheric pressure, to provide a continuous in-line processing of crystalline silicon solar cells. This paper presents the use of plasma chemical etching using Fourier Transform infrared (FT-IR) spectroscopy to monitor different silicon wafer processing steps as an alternative to the widely used wet chemical processing approach.
The Semiconductor Equipment and Materials International (SEMI) International Standards Program has a proven track record of more than 35 years of facilitating standards for high-tech industries, and aims to apply its experience to the emerging PV industry. Unlike other pre-established industries, where standard activities are mainly initiated by mature companies with clear requirements to standards, the PV industry, with its huge number of newly founded companies, is currently focused on ramping up their production lines and stabilizing their production processes. By structuring and utilizing standards requirements, it is possible to focus recourses to the most valuable standards in this critical phase of the fast-growing PV industry. SEMI intends to achieve these goals by proving recommendations for new standards activities, linking experts together to accomplish the deliverables, and speed up the process of standards deployment.
Inline processing, one of the fastest-growing production processes for crystalline silicon solar cells, uses continuously operated belt furnaces to achieve higher overall throughput compared with traditional batch processing. A second, major advantage of inline processing is improved manufacturing yields through reduced breakage of today’s thinner, increasingly delicate wafers. This is accomplished by eliminating several handling steps unique to batch processing techniques. This paper describes the influence of ECN-Clean, as developed by Mallinckrodt Baker and ECN in 2006, whose application increases the efficiency of solar cells produced using inline processing by approximately 0.3 percent absolute, compared with standard inline processing.
Investments in large photovoltaic factories can lead to high capital expenditure. To achieve a fast return on investment, it is essential to ensure a high utilization of process equipment. Optimization of photovoltaic factory performance requires a fundamental understanding of the processes as well as of the material flow and manufacturing equipment. Fraunhofer IPA has developed an approach to gather and analyze the factory data in order to detect and understand the logistic influencing factors. With this factory data, the performance of material flow systems and production equipments can be evaluated, leading to detection and elimination of inefficiencies in the manufacturing lines. The methods of acquiring and analyzing factory performance data as outlined in this article mainly focus on thin-film manufacturing lines, but are also applicable to crystalline technologies.
A new wafer technology, named CDS (Crystallization on Dipped Substrate), is under development and has been found to be effective in the reduction of wafer cost and silicon feedstock. CDS technology was applied to 156mm x 156mm-sized wafers, obtained via the throughput of 1825cm2/min, and the resulting cell efficiency of 14.8% was confirmed. This paper outlines the principle behind the technology and outlines the procedure.
A vast majority of silicon solar cells are manufactured using silver paste that is screen printed onto the front side of the wafer and fired to form the front-side contact. Though this method is well established within the industry, it continues to present several areas for potential efficiency improvements. The Fraunhofer Institute [1] has, among others, studied the potential of using electrodeposition of silver on top of the front side silver paste as a way to improve the front-side contact and increase cell efficiency. These results have shown cell efficiency increases of up to 0.4% absolute. This type of improvement has captured the interest of many manufacturers, but there has been a hesitancy to adopt electrodeposition as there is uncertainty as to what they can expect on their cells. Since efficiency gains are dependent upon many factors that can be unique to an individual cell, this paper provides a much-needed exploration of the potential effects of electrodeposition of silver in a way that isolates its effects from that of other factors.
Crystalline wafer and thin-film photovoltaics manufacturing have experienced dramatic expansion in recent years, but future growth requires increasingly effective strategies to reduce costs and increase the competitiveness of PV power. Reducing PV manufacturing costs has been a prime focus of the industry. In the current climate, cost reduction is especially critical given the industry shakeout that many analysts are forecasting. Now more than ever, it is important to bring manufacturing capacity online quickly and cost effectively. The vast majority of commercial-scale PV manufacturing capacity is new construction (greenfield), meaning it is purpose-built on an unused piece of land; however, there are alternatives. This paper will outline opportunities for re-use of existing obsolete semiconductor fabs, and the steps required to convert from one manufacturing strand to another.
Today’s PV industry is growing at a rapid rate, but the industry would grow even faster if costs could be reduced for both the final products and the capital investment required for scale-up. One strategy for reducing module cost is to reduce the amount of semiconductor material needed (the cost of the silicon solar cells typically comprises more than half of the module cost). Many companies are thinning the silicon wafers to reduce costs incrementally; others use thin-film coatings on low-cost substrates (such as amorphous/microcrystalline silicon, cadmium telluride, or copper indium gallium (di)selenide on glass or other substrates). Concentrating photovoltaics (CPV) follows a complementary approach and uses concentrating optics, which may be designed for low or high concentration, to focus the light onto small cells. Low-concentration concepts use silicon or other low-cost cells; high-concentration optics may use more expensive, higher-efficiency cells. The higher-efficiency cells can reduce the cost-per-watt if the cost of the small cells is minimal.
Solar enterprises will each be faced with the occasional surplus or lack of solar modules in their lifetimes. In these instances, it is useful to adjust these stock levels at short notice, thus creating a spot market. Spot markets serve the short-term trade of different products, where the seller is able to permanently or temporarily off-set surplus, while buyers are able to access attractive offers on surplus stocks and supplement existing supply arrangements as a last resort.
Standardized requirements for the quality of PV modules, solar cells and wafers are given in the according IEC norms (e.g., IEC 61215, 61646, and IEC 61730 for modules). However, the manufacturers of cells purchasing wafers and the module manufacturers purchasing cells want information beyond the final check of the product and to monitor each step during the production process to identify harsh handling and/or machine faults at the earliest stage possible. With consequential improvements of the process enabled, continuous improvements in throughput and yield improvement of the factory are likely, also allowing an early feedback on quality issues to the raw material supplier. Furthermore, by knowing all characteristics and factors of the cell and the module, prediction of electrical energy yield during the life cycle of a PV power plant is becoming more accurate and more reliable.
