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19.31%-efficient multicrystalline silicon solar cells using MCCE black silicon technology

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By Xusheng Wang, Shuai Zou & Guoqiang Xing, Canadian Solar Inc. (CSI)

A novel nanoscale pseudo-pit texture has been formed on the surface of a multicrystalline silicon (mc-Si) wafer by using a metal-catalysed chemical etching (MCCE) technique and an additional chemical treatment.
A desirable nanoscale inverted-pyramid texture was created by optimizing the recipe of the MCCE solution and using a proprietary in-house chemical post-treatment; the depth and width of the inverted pyramid was adjustable within a 100–900nm range. MCCE black mc-Si solar cells with an average efficiency of 18.90% have been fabricated on CSI’s industrial production line, equating to an efficiency gain of ~0.4%abs. at the cell level. A maximum cell efficiency of 19.31% was achieved.

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The thirty-fifth issue of Photovoltaics International brings you insights into how investment in high-efficiency cell technology production appears to be showing no signs of slowing down and more about scientists from the R&D team at Canadian Solar look at so-called ‘black’ silicon, one of the new cell technology concepts beginning to gain currency. Additionally, how researchers from Germany’s Fraunhofer ISE take up the theme with a paper exploring the question of quality control in the production of high-efficiency silicon solar cells and not forgetting the growing importance of thin-film technologies in the overall PV mix.

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