Technical Papers

As polysilicon producers perform expansions and upgrades to increase production and improve operations, plant safety remains critical. Companies should routinely review their safety policies and effectively plan their projects to ensure uninterrupted product supply and create a safe environment for employees and the communities in which they operate. Both the design and the execution of expansion and upgrades to projects are critical as companies strive for minimal down time so that productivity is not affected. Such hazards and scenarios that may hinder and delay start-up, specifically in relation to polysilicon plants, are highlighted in this paper. Furthermore, the paper outlines how best to avoid these situations, offering methods of execution to achieve the three key measures of success: safety, high purity and minimal downtime.

Upgraded metallurgical-grade (UMG) silicon is a lower cost and lower quality form of solar-grade silicon that is capable of producing solar cells at over 16% efficiency. This paper presents some of the economic advantages and technical concerns and solutions associated with producing silicon based PV from UMG, as well as preliminary solar cell results using this material. Results are based on a comparison of cells made in a turnkey line (Schmid Group) using alloy blends of 10%, 20%, 30% and 100% UMG, mixed with solar-grade Si before ingot growth. Detailed characterization was carried out on these finished cells according to lifetime, LBIC, diffusion length and luminescence imaging to determine correlations of performance with basic parameters. Requirements for material cost and cell performance necessary for UMG solar cells to be cost competitive are also presented.

Interconnection of inverters to the electrical grid is a key issue for the widespread integration of distributed energy resources, especially when the scenario surrounding international standards is so unclear. As a pre-normative research step, a round-robin test of two small-scale photovoltaic inverters was performed by nine DERlab laboratories during 2009. The test activity was focused on the verification of individual test procedures, common interpretation of standards and requirements, and determination of problems related to the equipment and facilities involved in conducting roundrobin.

An improved understanding of multicrystalline wafer quality can explain variations in cell performance across multicrystalline silicon blocks. Infrared scanning can detect precipitates in a silicon block, while photoluminescence combined with defect etching can reveal needle-like precipitates along the grain boundaries. Such precipitates typically lead to reduced shunt resistance. Crystallographic defects that lower the current collection and the final cell efficiency can also be identified. Understanding the influence of these defects is important for the development of a crystallization technology that results in a substantially better cell efficiency. The use of the improved material quality in an innovative cell and module technology have led to the world record module efficiency of 17%. This paper will illustrate one example of how an improved understanding of multicrystalline wafer quality can explain the variations in cell performance.

This paper, the third in a series covering cost of ownership (COO) studies for photovoltaics [1], examines the need for metallization of silicon-based solar cells and how it has evolved over the past few years. The technologies and techniques that are being developed for this part of cell manufacturing in the foreseeable future are also discussed. The paper will conclude with a COO case study using the DEK Solar PV3000 as an example.

This article will look at what trends can be gleaned from patent application publication figures of the past decade in the sector of PV technology. The study looks at the number of patent applications in PV technology published worldwide between 1999 and 2008. The data will show in which regions and countries patent protection is being sought. The figures are taken from patent documentation databases developed by the European Patent Office (EPO) and Japan Patent Office or databases used worldwide and available at the EPO, and they are retrieved mostly using patent classification schemes. The article also provides a brief overview of the role of the EPO and what companies, researchers and individual inventors should keep in mind when applying for a European patent.

With the ever-growing challenge of remaining financially viable in today’s economic climate, some companies in the PV industry are adapting and applying the structures and principals of project finance to the photovoltaic assets. The purpose of project finance is to create a business structure which brings together multiple entities, aligns their interests, and allocates the project’s inputs and outputs (i.e. risks and rewards) in such a way that the overall benefits derived from the project are maximized.

Among the different packaging materials used in photovoltaic solar modules, ethylene vinyl acetate-based (EVA) encapsulants play an important role during the lifespan of the module assembly. Prior to lamination, EVA is a thermoplastics polymer containing a number of additives. During the lamination process, EVA cross-links into a three-dimensional network structure, i.e., a thermoset, which provides protection for solar cells against detrimental environmental conditions. Since EVA has a very low glass transition temperature and melting points, proper cross-link density has to be achieved through the lamination process to prevent the EVA from cold flowing in the field. As a result, module manufacturers constantly monitor the cross-link density or gel content of EVA after lamination. This paper proposes a new method of measuring this density value while avoiding many of the current pitfalls.

Until the year 2002, wafer-based crystalline silicon solar cells were almost exclusively the solar cell technology used for large-scale power plants. Since then, steady growth in the market share for thin-film technologies has been observed, although crystalline silicon technology still remains the most important solar cell technology used in large-scale PV power plants. The market share of thin-film modules, especially CdTe modules, has been continuously increasing in recent years, most notably in the German market. However, other countries like Spain, the USA, Italy and France have seen some large-scale CdTe-based modules being installed in power plants recently.

Solar enterprises will each be faced with the occasional surplus or lack of solar modules in their lifetimes. In these instances, it is useful to adjust these stock levels at short notice, thus creating a spot market. Spot markets serve the short-term trade of different products, where the seller is able to permanently or temporarily offset surplus, while buyers are able to access attractive offers on surplus stocks and supplement existing supply arrangements as a last resort.