PVI Issue

Photovoltaics International Volume 23

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This issue of Photovoltaics International, our 23rd, offers key insights into some of the technologies that are ready to move from lab to fab in support of these goals. ISC Konstanz offer a glimpse of what the low-cost, high-efficiency solar cells of the future might look like. On page 35 the institute’s authors give an overview of what they call Konstanz’ “technology zoo”, encompassing their so-called BiSoN, PELICAN and ZEBRA cell concepts, all of which are aimed at increasing energy yield at the lowest possible cost.

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In this issue...

PVI Paper
Photovoltaics International Papers, PV Modules
Recent advances at the cell level and in tabber-stringer equipment have led to the development of the next generation of cell interconnection architecture, resulting in an increase in cell and module performance. The multi-busbar (MBB) concept discussed in this paper delivers the benefits of a saving in material costs, a reduction in total series resistance and an improved light utilization for higher performance at lower cost. The combination of the cell and module concept and the stringer equipment works for a wide variety of cell types and enables an appreciable decrease in cost per watt and module size per watt.
PVI Paper
Photovoltaics International Papers, Power Generation
The pioneers of utility-scale PV construction have drawn on methods used in other industries to make power plants more efficient and more competitive. This paper investigates how cutting-edge techniques in modularndesign are being used to drive down plant costs. The evolution of modular design and its attractiveness to theinvestor community are discussed.
PVI Paper
Materials, Photovoltaics International Papers
Metal wrap-through (MWT) module technology is an attractive approach for increasing module efficiency. This paper shares the results of MWT module fabrication using a silicone electrically conductive adhesive (ECA), a conductive backsheet (CBS) with a thin organic layer surface finish, and an automated module assembly line. Very low cell-to-module (CTM) power losses are observed, leading to a multicrystalline Si module power of 266W and a full-area efficiency of 16.8%. The modules are very stable in damp-heat conditions and thermal cycling, demonstrating minimal degradation after 1.5 x IEC requirements in terms of damp heat and thermal cycling, and well below 2% degradation after 2 x IEC requirements. These MWT modules have received IEC 61215 and IEC 61730 certification.
PVI Paper
Photovoltaics International Papers, Thin Film
This paper describes the degradation of sputtered aluminium-doped zinc oxide (ZnO:Al) layers which were exposed to damp heat (85°C/85% relative humidity). The ZnO:Al samples were characterized by electrical, compositional and optical measurements before, during and after damp heat exposure. Hall measurements showed that the carrier concentration stayed constant, while the mobility decreased and the overall resistivity thus increased. This mobility decrease can be explained by the enhancement of the potential barriers at the grain boundaries because of the occurrence of additional electron-trapping sites. X-ray diffraction (XRD) and optical measurements demonstrated that the crystal structure and transmission in the range 300 –1100nm did not change, thereby confirming that the bulk structure stayed constant. Depth profiling showed that the increase of the potential barriers was caused by the diffusion of H2O/OH- through the grain boundaries, leading to adsorption of these species or to the formation of Zn(OH)2 or similar species. Depth profiling also revealed the presence of carbon, chloride and sulphide in the top layer, which indicates the possible presence of Zn5(CO3)2(OH)6, Zn5(OH)8Cl2•H2O and Zn4SO4(OH)6•nH2O. Furthermore, white spots appeared on the ZnO:Al surface during damp heat exposure. The spots contained elements, such as silicon and calcium, which might have migrated from the glass and which reacted with species from the environment, including oxygen, carbon and chlorine.
PVI Paper
Photovoltaics International Papers, PV Modules
The SPF solar glass certification was developed in 2002 to guarantee the quality of glazing for use as a transparent cover for solar thermal collectors. More than 200 glass types from leading manufacturers have been measured and certified to date. Despite the certification having been explicitly developed for solar thermal applications, it became widely used in the PV module industry, even though the results are not transferable and may lead to erroneous conclusions in some cases. In 2012 the certification was therefore adapted to the needs of the PV industry, and a dedicated PV solar glass certification has since been available. This paper explains the fundamentals of the certification process, which consists of three performance characterizations: 1) transmissivity, 2) incident angle modifier (IAM), and 3) UV degradation. Results are discussed for different representative glass types, including float glass, anti-reflective-coated glass and rolled glass with different structures. Furthermore, the performance of these glass types when used as covers of crystalline silicon PV modules is compared. The examples presented also highlight the advantages of the adapted characterization methods compared with standard glass measurements.
PVI Paper
Cell Processing, Photovoltaics International Papers
Although considerable progress has been made in reducing the amount of Ag required per wafer in the classic screen-printing metallization of Si solar cells, the total cost of ownership of the metallization process today accounts for more than 50% of the total cell-process-related cost. There has been pressure on cell and module manufacturers to further reduce this cost, by either improving the metallization process or applying alternative contacting technologies. In this paper, the classic screen printing of standard Si-based solar cells, which has been the main metallization technique for many years, is described in detail. The required paste volume for providing the contacts in a state-of-the-art cell production process is calculated on the basis of the contact dimensions (fingers and busbars on the front, Al layer and Al/Ag pads on the back). Taking into account today's paste prices, equipment investment, screen cost, energy, maintenance, yield, material utilization and necessary labour, the total cost of ownership of the cell metallization is also determined. The main cost drivers are discussed in detail. The cost reduction is estimated when improved printing processes – such as double, dual or stencil printing – are employed. Other promising alternative front-contact metallization technologies are listed and their potential is briefly discussed. To evaluate the competitiveness of these technologies, the limit of today's screen-printing method and its further cost reduction potential are estimated on the basis of the physical properties of cells and printing pastes.
PVI Paper
Fab & Facilities, Photovoltaics International Papers
The investment case for the establishment of PV manufacturing hubs in emerging regions became bleak as c-Si PV manufacturing capacities in China ballooned from 2004 to 2011/12. The resulting supply overhang, with dramatic price decreases throughout the PV value chain, led to severe margin compressions and ultimately to closures, insolvencies and postponement of expansion plans by incumbents across the board. A common misperception by private and public decision makers alike – reflected in the recent escalation in global trade disputes – is that products made outside China are, per se, not competitive. In contrast to this mind-set, and on the basis of experience in numerous development projects, the author argues that new entrants have multiple instruments available that can make local PV manufacturing plants commercially viable in many regions of the world.
PVI Paper
Photovoltaics International Papers, PV Modules
Ethylene vinyl acetate (EVA) is still the dominant material used for encapsulation of solar cells. During PV module lamination, a three-dimensional network is formed by a chemical cross-linking of the polymer chains in order to increase the thermal stability of the material and to prevent the material from melting when exposed to application-relevant temperatures of up to 100°C. The cross-linking reaction, which is discontinuous and can take up to 30 min (depending on the EVA type), is the time-determining step in PV module lamination. The main objective of this paper is to gain a comprehensive understanding of the thermomechanical material behaviour during the PV module lamination process, and to develop a basis for the optimization of the PV module manufacturing process. The results presented will demonstrate that dynamic mechanical analysis (DMA) is a valuable and reliable characterization method for the investigation of the curing behaviour of EVA for solar cell encapsulation. DMA in shear mode allows a continuous measurement of the thermomechanical properties, even in the molten state, and therefore an in situ monitoring of the cross-linking reaction. Whereas it is possible to use temperature scans on partially cured EVA films to determine the state of cross-linking, isothermal scans on uncured samples allow the curing kinetics of EVA to be investigated. On the basis of an enhanced knowledge of the cross-linking reaction, the material-related process-parameter optimization potential of the PV module lamination process can be identified, and optimum processing temperature ranges and minimum cross-linking times can be derived.
PVI Paper
Cell Processing, Photovoltaics International Papers
After several years of crisis, the PV manufacturing industry is expected to pick up again from 2014 onwards, and cell and module producers will consequently expand their production capacities in the coming years. To obtain high margins, producers must introduce new products that are better performing in terms of electrical performance and lifetime, even under harsh climatic conditions (e.g. in desert regions). This requires the use of innovative technologies that not only allow low production costs (US$/Wp), but also guarantee at the same time high module efficiencies and – even more importantly – high energy yields in terms of kWh over the entire lifetime of the system. This means that the most promising advanced cell concepts will use a limited number of standard industrial process steps and proven standard equipment. For at least the next five (probably more) years, high efficiency (>20%) at a reasonable cost will still be achieved with crystalline silicon-based technology alone. The research and development at ISC Konstanz therefore concentrates mainly on cell concepts that can be implemented using standard tube furnace diffusions and screen-printed metallization, with a focus on n-type-based technologies. This paper gives an overview of ISC Konstanz's technology zoo, including BiSoN, PELICAN and ZEBRA cell concepts, which are ready for industrial implementation. In addition, the integration of these innovative cells into modules, along with the importance of various features – such as bifaciality – in increasing the energy yield, is discussed.

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