Technical Papers

The minority carrier lifetime is a key parameter for the performance of solar cells as it characterizes the electrical quality of the semiconductor material. Consequently, accurate and reliable methods to determine the minority carrier lifetime are of enormous interest for both practical process control and the evaluation of the potential and limitations of a specific cell concept. Due to its importance, many different lifetime measurement techniques have been developed and used over the past few decades. This paper aims to present and discuss the most common measurement methods on the one hand, while attempting to shed light on some recent developments on the other. The determination of the minority carrier lifetime of crystalline silicon thin-film (cSiTF) material is illustrated as an example of interest for those who are already familiar with standard lifetime characterization.

The next generation of industrial silicon solar cells aims at efficiencies of 20% and above. To achieve this goal using ever-thinner silicon wafers, a highly effective surface passivation of the cell, front and rear, is required. In the past, finding a suitable dielectric layer providing a high-quality rear passivation has been a major challenge. Aluminium oxide (Al2O3) grown by atomic layer deposition (ALD) has only recently turned out to be a nearly perfect candidate for such a dielectric. However, conventional ALD is limited to deposition rates well below 2nm/min, which is incompatible with industrial solar cell production. This paper assesses the passivation quality provided by three different industrially relevant techniques for the deposition of Al2O3 layers, namely high-rate spatial ALD, plasma-enhanced chemical vapour deposition (PECVD) and reactive sputtering.

Despite the financial crisis and present credit crunch, photovoltaic materials markets experienced only a temporary slide in demand in 2009, with the overall outlook remaining optimistic. This paper presents a strategic analysis review for the materials used in photovoltaic modules, essentially materials for encapsulant, frontsheet, backsheet and anti-reflection coatings. Rising concerns about the need to reduce CO2 emissions and increase the use of renewable energy sources worldwide will stimulate the global photovoltaic market. Feed-in tariffs and politically backed targets boosting renewable energy use will provide further impetus to the photovoltaic market. This, in turn, will have a positive ripple effect on the demand for photovoltaic materials; however, depending on the market share for technology used, i.e. crystalline or thin film for PV energy, the market for materials will be influenced, in addition to advantages and disadvantages of these materials that will influence their market share. With rising awareness about green trends, the future will lie in technologies that offer enhanced energy-efficient solutions at a low cost. Manufacturers who offer products with optimum performance while remaining price-orientated will be poised to gain substantial market share.

PV industry module and component manufacturers have brought down costs significantly over the last four years. This trend is clearly evident as most publicly traded companies continue to grow revenue despite falling module and component prices. However, it is far less clear how downstream system integrators are handling the drop in system prices and contributing to value creation. System prices are generally higher in the U.S. than in Europe despite lower module prices in the U.S. This disparity often raises questions on the part of European PV professionals where these costs come from, and secondly, what have U.S. system integrators done to reduce costs. This article is the second of a two-part series shedding light on how U.S. integrators contribute to a decreasing installed-PV-system cost roadmap by championing value creation in the downstream segment. Focusing on the residential market segment, Part I delved into activity cost savings through innovation in engineering and construction [1]. Part II illustrates how changes in marketing and sales, rebates, interconnection, supply chain management and customer support have evolved considerably over the last several years to result in reduced costs.

Solar enterprises will each be faced with the occasional surplus or lack of solar modules in their lifetimes. In these instances, it is useful to adjust these stock levels at short notice, thus creating a spot market. Spot markets serve the short-term trade of different products, where the seller is able to permanently or temporarily offset surplus, while buyers are able to access attractive offers on surplus stocks and supplement existing supply arrangements as a last resort.

This paper, the fourth in a series covering cost modelling studies for photovoltaics [1–3], examines a new approach to module assembly based on the concept of ‘supersized’ 1kW PV modules. Using supersized modules (1.6m × 3.8m) and integrated microinverters, this novel approach has the estimated potential to save utility solar installations nearly $0.50/Watt. The paper will conclude with a detailed cost and resource case study comparing two 40MW module lines, one employing ‘solar breeder’ technology and the other producing conventional-sized modules.

This paper presents fluorescence detection as a new tool for the investigation of the degradation of EVA. The superior sensitivity of the set-up contained herein allows an early assessment of the changes of the EVA after only 20 hours of damp-heat exposure. A newly developed scanning system allows the spatially resolved inspection of entire PV modules. Degradation of the encapsulants was detectable after two years’ outdoor exposure, as was the effect of cracks in c-Si cells, which coincide well with cracks made visible by electroluminescence.

The three most viable thin-film photovoltaic technologies – cadmium telluride (CdTe), copper-indium gallium (di)selenide (CIGS), and amorphous silicon (a-Si) – continue to mature and grow technologically and in market stature. But apart from the dominance shown by CdTe leader First Solar, the rest of the TFPV manufacturers have had a fairly difficult time making significant commercial inroads as the price of mainstream crystalline-silicon modules plummeted over the past couple of years. Other factors delaying the long-predicted age of thin film include bankability challenges and difficulties in reducing production and system costs. Yet entrants in all three thin-film categories have reason for optimism, as they push toward a competitive market position. This paper provides an overview of the current status of the thin-film PV sector and its players, offering insights into why certain companies might emerge successfully in the years ahead.

Magnetron-sputtered ZnO:Al is often used as a front contact in thin film silicon solar cells due to its transparent conductive oxide (TCO) properties that allow texturization by chemical etch processes to introduce light trapping. The transparency, conductivity, and surface texture after etching depend strongly on the sputtering conditions. Consequently, the typical preparation method is to find the right balance in TCO properties and light scattering, leading to a very narrow sputtering parameter window. It is preferable to separate the electro optical optimization from that of texturization to allow for a larger process window and improve ZnO:Al film properties further. This paper presents some methods of controlling the surface features using various mixtures of two step etching processes in aqueous solutions of HF and HCl. Results include methods for controlling the density of craters, texturizing compact ZnO:Al films, and fabricating novel modulated surfaces with more than one characteristic feature size. The two step etch process enables the creation of good surface textures even on high rate material that, via state of the art HCl etching, tend to lead to poor solar cell performance.

Highly conductive transparent films are of significant interest in the field of thin-film photovoltaics. The solar cell type defines the necessary properties of the TCO used, as, besides the obvious qualities of transparency and conductivity, stability and morphology are important. The most significant properties of these aspects for front contacts in amorphous/microcrystalline silicon tandem, CIGS and CdTe solar cells are presented in this paper. Commonly used deposition techniques like CVD and sputter technology are described herein, focusing on particular techniques like SnO2:F and ZnO:B (CVD) and ZnO:Al (sputtering). New developments of deposition methods are also discussed.