As the PV industry rapidly advances towards annual PV production and installations on a terawatt scale, many aspects that are currently not critical will need to be considered. Among these, material availability is probably one of the most pressing ones. Established production routines will need to be changed, which may pose significant time constraints in the light of the fast-growing market. The focus of this paper will be on the use of silver for solar cell metallization. Past developments are discussed and an overview is given of the fast-growing number of relevant publications from the scientific community that deal with the problems associated with silver.