Technical Papers

To achieve project cash flow expectations, it is necessary to operate, maintain and optimize the performance of a PV power asset to meet or exceed the pro forma operating assumptions. To assume as given the achievement of these model assumptions is both naive and risky. Experience in operating the largest fleet of solar PV power plants in the world has demonstrated that project financial hurdle rates can be missed by as much as 25% if the plant is not well maintained and its performance is not optimized. Conversely, an optimized PV asset can generate cash flows 2–10% higher than expected if the optimization approach described in this paper is implemented.

Economics will always play a crucial role in the way PV technology advances. However, the current generation of products is facing substantial business challenges in the attempt to scale the product technologies. This paper is the fifth in a series covering business analysis for PV processes. The methods applied in these papers fall into two categories: cost of ownership (COO) modelling and cost and resource modelling. Both methods examine the business considerations associated with the adoption of new processes, tools or materials. This is more critical than ever. Nearterm issues – in some cases the survival of the business – heavily influence today's decision processes. This paper tries to identify the areas that it is thought will produce the largest near-term paybacks. The areas identified are n-type wafers, Al2O3 passivation and copper metallization.

Electroluminescence (EL) imaging for photovoltaic applications has been widely discussed over the last few years. This paper presents the results of a thorough evaluation of this technique in regard to defect detection in photovoltaic modules, as well as for quality assessment. The ability of an EL system to detect failures and deficiencies in both crystalline Si and thin-film PV modules (CdTe and CIGS) is thoroughly analyzed, and a comprehensive catalogue of defects is established. For crystalline silicon devices, cell breakages resulting from micro-cracks were shown to pose the main problem and to significantly affect the module performance. A linear correlation between the size of the breakages and the power drop in the module was established. Moreover, mechanical stress and temperature change were identified as the major causes of the proliferation of cracks and breakages. For thin-film modules, EL imaging proved the existence of an impressive reduction in the size of localized shunts under the effect of light-soaking (together with a performance improvement of up to 8%). Aside from that, the system voltage was applied in order to monitor transparent conductive oxide (TCO) corrosion effects and laser-scribing-induced failures, as well as several problems related to the module junction box in respect of its sealing and the quality of its electric connectors.

Because potential-induced degradation (PID) can cause power losses of more than 30% for modules out in the field, there has already been an extensive effort placed on avoiding this adverse phenomenon. A key feature at the cell level is the silicon nitride (SiNx) anti-reflective coating (ARC). Apart from the known dependency of PID susceptibility on the refractive index, the impact of the deposition parameters has also been under investigation. This paper illustrates the influence of different silicon nitrite layers and their ability to prevent PID. A large number of cells and modules were therefore manufactured, differing only in the type of ARC. The modules were subsequently PID tested under three different climatic conditions, and acceleration factors and activation energies were determined from these tests. In addition this paper presents the results of addressing the weak-light performance and the hot-spot risk of panels after PID exposure. Finally, the reversibility of PID was also investigated in relation to the state of degradation of these samples.

Since the demonstration of the first CuInSe2 solar cell in 1974 by scientists at Bell Laboratories, a lot of effort has been put into the development of cost-effective processes for highly efficient Cu(In,Ga)(Se,S)2 – or CIGS – solar cell devices. In 2012 these efforts led to the first gigawatt CIGS solar module production facility operated by Solar Frontier, a company that has a long history in R&D and originates from ARCO Solar, who developed the first commercial CIGS solar modules at the beginning of the 1990s. However, several start-up companies employing CIGS technology are presently struggling in the currently harsh market environment. Even though world-record laboratory solar cells now demonstrate 20.3% efficiency using a three-stage co-evaporation process, and full-size modules achieve 14.6% employing a similar method, efforts in research and development are more important than ever in order to increase cell efficiency, to bridge the gap between cell and module efficiencies, and to develop cost-effective and robust manufacturing processes. This paper gives an overview of current research topics under investigation by research institutes and industry, with a main focus on CIGS absorber formation. Along with other research results published by groups all over the world, this paper covers recent research results obtained at the Helmholtz-Zentrum Berlin für Materialien und Energie (HZB) and briefly mentions the work of the Photovoltaic Competence Center Berlin (PVcomB), a joint initiative of the Technical University of Berlin (TU Berlin) and HZB.

This paper presents the background and technology development of the use of ion implantation technology in today’s crystalline silicon solar cell manufacturing lines. The recent history of ion implantation development and commercialization is summarized, and an explanation is given for the cell efficiency improvements realized using the technique on p-type mono-crystalline cells. The potential economic impact on the factory is also discussed.

Reducing the cost of photovoltaic energy is the main objective of solar cell manufacturers. This is ideally realized by increasing cell efficiency and simultaneously decreasing manufacturing cost. To reduce fabrication costs, the international roadmap of photovoltaics (ITRPV) forecasts a reduction in cell thickness from 180μm to 120μm in the next six years, and even thinner cells may be desirable, as long as efficiency and yield are not negatively affected. In order to increase efficiency, the ITRPV forecasts an increase in share of back-contacted cells from 5% to 35% in the next eight years. In this paper the dependence of the efficiency of back-junction back-contact (BJBC) solar cells on cell thickness is investigated experimentally and numerically. To this end, BJBC silicon solar cells with cell thicknesses ranging from 45μm to 290μm are fabricated and simulated. Thinned float-zone material is used as well as monocrystalline epitaxial layers fabricated by the porous silicon process for 45μm-thick cells. The efficiency of the best cell is 22.6% (130μm cell thickness) and 18.9% for an epitaxial cell (45μm thickness). Loss mechanisms in the maximum power point of all cells are investigated by using a freeenergy loss analysis based on finite-element simulations. A lower generation and a lower recombination in thinner cells compete against each other, resulting in a maximum efficiency of 20% for a cell thickness of 45μm at a base lifetime of 20μs. At a base lifetime of 3000μs, the maximum efficiency is greater than 23% for a cell thickness beyond 290μm, but reducing the cell thickness from 290μm to about 90μm results in a power loss of less than 0.6% absolute.

A record-low spot price in the wake of oversupply and the aggressive cost-reduction roadmap of the PV industry are putting polysilicon producers under pressure to bring down their manufacturing costs. With the dominant Siemens process approaching a limit for further cost cuts, technologies based on the deposition from monosilane (SiH4) have now become the focus of attention.

The cost of PV modules manufactured and sold in 2012 is highly reliant on the materials used in the construction. A significant part of the market price is driven by the bill of materials, while other direct costs and depreciation form a small proportion of the total cost. Changes within the supply chain, and in the cost of the materials needed and used, are extremely important influences on the module cost and the end market price. In 2012 we have seen a slowdown in growth in the installation of both commercial and residential PV, despite dramatic falls in module costs. Some of the trends and effects of these changes on the materials supply chain for PV modules will be examined in this paper.

Production equipment is the backbone of the PV industry, but the equipment sector is suffering because of overcapacity. The 2012 global capacity utilization is at 55% for crystalline silicon (x-Si) module production, 70% for cadmium telluride (CdTe) and 80% for copper indium gallium (di)selenide (CIGS). Under these market conditions, there are almost no expected capacity expansions in the near term. The overcapacity has driven the average selling price (ASP) for modules significantly lower, resulting in hyper-competition in the PV industry, where almost all PV companies recognize the importance of product differentiation while still reducing costs. These market conditions present an opportunity for equipment manufacturers to differentiate their offerings through enabling lower production costs and higher efficiency of cells and modules.