‘Double world record’ for perovskite tandem solar cells claimed by EPFL, CSEM

The researchers tested two types of perovskite-on-silicon-tandem solar cells. Image: CSEM

Researchers at EPFL’s Photovoltaics and Thin Film Electronics Laboratory and CSEM’s Sustainable Energy Centre have claimed two world records by achieving an efficiency of over 30% for perovskite-on-silicon-tandem solar cells.

The results have been independently certified by the US DOE’s National Renewable Energy Laboratory (NREL), the organisations said.

“These results are a boost to high-efficiency photovoltaics and pave the way toward even more competitive solar electricity generation.”  

They said that current solar cells are “fundamentally limited by the materials they are made from” because they are silicon-based with maximum efficiencies predicted to be 29%, while current efficiencies standing at around 27%, leaving little room for improvement.

The researchers said they had improved the efficiency of two kinds of perovskite-on-silicon tandems. First, they deposited perovskite layers from solution on a planarised silicon surface, reaching a power conversion efficiency of 30.93% for a 1cm squared solar cell.

Second, they used a hybrid vapor/solution processing technique compatible with textured silicon surfaces to produce a solar cell with a power conversion efficiency of 31.25% (again on 1cm squared cell).

“These results constitute two new world records: one for the planar and one for the textured device architecture. The latter approach provides a higher current and is compatible with the structure of current industrial silicon solar cells,” the researchers said.

“Halide perovskites have been identified as an ideal partner for silicon, as they can convert visible light more efficiently to electrical power in comparison to silicon alone, without overly increasing fabrication costs,” the research institutes said.

“We have passed a psychological barrier,” said Christophe Ballif, head of the EPFL Photovoltaics Laboratory and CSEM’s Sustainable Energy Centre. “We have validated experimentally the high-efficiency potential of perovskite-on-silicon tandems.”

While, the 30% efficiency mark has already been achieved with other types of materials, namely III-V semiconductors, Ballif said “these materials and the processes used to make them are too expensive to sustain the energy transition”.

“Our results are the first to show that the 30% barrier can be overcome using low-cost materials and processes, which should open new perspectives for the future of PV.”

In June, Researchers at NREL found that a tin-lead perovskite cell can overcome problems with stability and improve efficiency, with their experiment yielding a 25.5% conversion efficiency.

In March, researchers at the Polytechnic University of Milan found that the chemical process of halogen bonding has “considerable potential for the development of a new generation of solar cells based on perovskites”, while a month earlier researchers in Saudi Arabia reported the “the first ever” successful damp-heat test of perovskite solar cells, which they claim has moved the technology closer towards commercial viability.

11 October 2022
PV CellTech Extra will be held as a series of live webinars and on-demand sessions on 11-13 October 2022. We'll be taking a slightly further forward-looking view at the technologies and roadmaps for new cell architectures set to dominate mass production during 2023-2025 with special emphasis on the potential timelines for technologies beyond the single-junction cell design, including perovskite and hybrid concepts.

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